Coordination Cages

cage

Self-assembly is the most promising approach to build organic nanostructures on surfaces, leading to hybrid organic-inorganic materials. The idea behind this approach is to exploit the thermodynamic control and reversibility of self-assembly for the error-free generation of 3D architectures, like coordination cages, directly on surfaces, which is one of the key requirements for the development of nanotechnology and molecular electronics. The extension of the self-assembly protocol to technologically interesting surfaces, like silicon, allows to build hybrid inorganic-organic structures featuring selective inclusion and other useful properties. The generation of such complex organic architectures on silicon will be pivotal in developing new integrated devices presenting peculiar optic, magnetic and sensing properties.

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Selected publications

P. Jacopozzi, E. Dalcanale, Metal-induced Self-assembly of Cavitand-based Cage Molecules, Angew. Chem. Int. Ed. Engl. 1997, 36, 613-615.

S. Levi, P. Guatteri, F.C.J.M. van Veggel, G.J. Vancso, E. Dalcanale, D.N. Reinhoudt, Direct Observation of Surface Controlled Self-assembly of Coordination Cages by an AFM as Molecular Ruler, Angew. Chem. Int. Ed. 2001, 40, 1892-1896.

F. Fochi, P. Jacopozzi, E. Wegelius, K. Rissanen, P. Cozzini, E. Marastoni, E. Fisicaro, P. Manini, R. Fokkens, E. Dalcanale, Self-assembly and Anion Encapsulation Properties of Cavitand-Based Coordination Cages, J. Am. Chem. Soc. 2001, 123, 7539-7552.

L. Pirondini, F. Bertolini, B. Cantadori, F. Ugozzoli, C. Massera, E. Dalcanale, Design and Self-Assembly of Wide and Robust Coordination Cages, Proc. Natl. Acad. Sci. USA 2002, 99, 4911-4915.

E. Menozzi, R. Pinalli, E.A. Speets, B.J. Ravoo, E. Dalcanale, D.N. Reinhoudt, Surface-Confined Single-Molecules: Assembly and Disassembly of Nanosize Coordination Cages on Gold (111), Chem. Eur. J. 2004, 10, 2199-2206.

R. Pinalli, V. Cristini, V. Sottili, S. Geremia, M. Campagnolo, A. Caneschi, E. Dalcanale, Cavitand-Based Nanoscale Coordination Cages, J. Am. Chem. Soc. 2004, 126, 6516-6517.

D. Zuccaccia, L. Pirondini, R. Pinalli, E. Dalcanale, A. Macchioni, Dynamic and Structural NMR Studies of Cavitand-Based Coordination Cages, J. Am. Chem. Soc. 2005, 127, 7025-7032.

M. Busi, M. Laurenti, G. G. Condorelli, A. Motta, M. Favazza, I. L. FragalĂ , M. Montalti, L. Prodi, E. Dalcanale, Self-Assembly of Nanosize Coordination Cages on Si(100) Surfaces, Chem. Eur. J.2007, 13, 6891-6898.

L. Pirondini, E. Dalcanale, Supramolecular 3D Architectures by Metal-directed Assenbly of Synthetic Macrocycles, Modern Supramolecular Chemistry: Strategies for Macrocycle Synthesis, (Eds. F. Diederich, P. Stang, R. R. Tykwinski), Wiley-VCH Verlag Gmbh & Co. KGaA, Weinheim, Germany, 2008, 233-276.

F. Gruppi, F. Boccini, L. Elviri, E. Dalcanale, Self-assembly of a Cavitand-based Heteronuclear Coordination Cage, Tetrahedron 2009, 65, 7289-7295.

M. Busi, B. Cantadori, F. Boccini, R. De Zorzi, S. Geremia, E. Dalcanale, Molecular Recognition with Ditopic Cavitand Re-Complexes, Eur. J. Org. Chem. 2011, 2629-2642.